Absolute helicity induction in three-dimensional homochiral frameworks.
نویسندگان
چکیده
Three Co(II) isomers assembled from D-, or L-, or DL-camphorate together with achiral isonicotinate exhibit a clear relationship between chirality and helicity even though chiral molecules are not in the backbone of the helix: the absolute sense of helix made of achiral components is controlled by chains of metal and enantiopure chiral ligands running perpendicular to helix in two enantiomeric forms.
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ورودعنوان ژورنال:
- Chemical communications
دوره 2 شماره
صفحات -
تاریخ انتشار 2009